We present a computational imaging method for raw material classification using features of Bidirectional Texture Functions (BTF). Texture is an intrinsic feature for many materials, such as wood, fabric, and granite. At appropriate scales, even "uniform" materials will also exhibit texture features that can be helpful for recognition, such as paper, metal, and ceramic. To cope with the high-dimensionality of BTFs, in this paper, we proposed to learn discriminative illumination patterns and texture filters, with which we can directly measure optimal projections of BTFs for classification. We also studied the effects of texture rotation and scale variation for material classification. We built an LED-based multispectral dome, with which we have acquired a BTF database of a variety of materials and demonstrated the effectiveness of the proposed approach for material classification.