As is well known, differential algebraic equations (DAEs), which are able to describe dynamic changes and underlying constraints, have been widely applied in engineering fields such as fluid dynamics, multi-body dynamics, mechanical systems, and control theory. In practical physical modeling within these domains, the systems often generate high-index DAEs. Classical implicit numerical methods typically result in varying order reduction of numerical accuracy when solving high-index systems. Recently, the physics-informed neural networks (PINNs) have gained attention for solving DAE systems. However, it faces challenges like the inability to directly solve high-index systems, lower predictive accuracy, and weaker generalization capabilities. In this paper, we propose a PINN computational framework, combined Radau IIA numerical method with an improved fully connected neural network structure, to directly solve high-index DAEs. Furthermore, we employ a domain decomposition strategy to enhance solution accuracy. We conduct numerical experiments with two classical high-index systems as illustrative examples, investigating how different orders and time-step sizes of the Radau IIA method affect the accuracy of neural network solutions. For different time-step sizes, the experimental results indicate that utilizing a 5th-order Radau IIA method in the PINN achieves a high level of system accuracy and stability. Specifically, the absolute errors for all differential variables remain as low as 10−6 , and the absolute errors for algebraic variables are maintained at 10−5 . Therefore, our method exhibits excellent computational accuracy and strong generalization capabilities, providing a feasible approach for the high-precision solution of larger-scale DAEs with higher indices or challenging high-dimensional partial differential algebraic equation systems.