Accompanying the successes of learning-based defensive software vulnerability analyses is the lack of large and quality sets of labeled vulnerable program samples, which impedes further advancement of those defenses. Existing automated sample generation approaches have shown potentials yet still fall short of practical expectations due to the high noise in the generated samples. This paper proposes VGX, a new technique aimed for large-scale generation of high-quality vulnerability datasets. Given a normal program, VGX identifies the code contexts in which vulnerabilities can be injected, using a customized Transformer featured with a new value-flow-based position encoding and pre-trained against new objectives particularly for learning code structure and context. Then, VGX materializes vulnerability-injection code editing in the identified contexts using patterns of such edits obtained from both historical fixes and human knowledge about real-world vulnerabilities.