We present the Positional Knapsack Problem (PKP), show that it is NP-hard and admits a Fully Polynomial-Time Approximation Scheme (FPTAS). This problem is a variant of the classical Binary Knapsack Problem (KP) in which the contribution of an item to the objective function varies according to the position in which it is added. The change in the valuation adds new properties to the problem that do not hold for KP as PKP is not a generalization of KP. Our FPTAS is based on a dynamic programming algorithm and uses a recursive rounding approach, which is necessary since the objective function depends on each item's value and position.