Exoskeleton robots found application in neurorehabilitation, telemanipulation, and power augmentation. The human–robot attachment system of an exoskeleton should transmit all the interaction forces while keeping the anatomical and robotic joint axes aligned. Existing attachment concepts were bounding the performance of modern exoskeletons due to insufficient stiffness for high-performance force control, time-consuming adaption processes, and/or bulkiness. Therefore, we developed an augmented attachment system for a recent fully actuated nine-degree-of-freedom upper limb exoskeleton. The proposed system was compared to a conventional solution in a case study with four participants. The proposed attachment system lowered the relative motion between the human and the robot under static loads for all defined landmarks by 45% on average. The occurrence of undesired contacts in the trials was mitigated by 74%, thus improving conditions for closed-loop force control. Furthermore, the proposed system adapted better to the user's anatomy facilitating more accurate alignment and less obstruction. On average, self-attachment took$\mathbf {43(8.3)}$$\mathrm{s}$to don(doff). Thereby, the alignment of anatomic landmarks had typically less than 15 mm offset to a thorough expert alignment, making self-attachment eligible. The augmented attachment system and the insights gained by the case study are expected to enable improvement of the physical human–robot interaction of exoskeletons.