Both GaN- and ZnO-based diluted semiconductors (DMSs) have recently attracted considerable interest fueled by theoretical predictions of ferromagnetic ordering in these materials above room temperature, making them especially attractive for spintronics. The intense experimental research that followed has revealed, however, a great deal of controversy. The local structure and magnetic behavior of GaN- and ZnO-based DMSs were found to depend strongly on a preparation technique and growth conditions for the materials of the same nominal composition and the reported results varied considerably from group to group. This problem highlighted clearly the lack of theoretical understanding of physical mechanisms underlying ferromagnetisms in these materials and the inadequacy of standard characterization techniques used to probe structural and magnetic properties of the DMSs. In this paper, we report on the recent progress in the theoretical and experimental studies of ZnO- and GaN-based DMSs and make special impact on critical discussion of experimental methods employed for investigation of their magnetic and optical properties.

ZnO is an attractive material for applications in electronics, photonics, acoustics, and sensing. In optical emitters, its high exciton binding energy (60 meV) gives ZnO an edge over other semiconductors such as GaN if reproducible and reliable p-type doping in ZnO were to be achieved, which currently remains to be the main obstacle for realization of bipolar devices. On the electronic side, ZnO holds some potential in transparent thin film transistors (TFTs) owing to its high optical transmittivity and high conductivity. Among the other promising areas of application for ZnO are acoustic wave devices, due to large electromechanical coupling in ZnO, and devices utilizing nanowires/nanorods such as biosensors and gas sensors and solar cells, since it is relatively easy to produce such forms of ZnO nanostructures, which have good charge carrier transport properties and high crystalline quality. Despite the significant progress made, there is still a number of important issues that need to be resolved before ZnO can be transitioned to commercial use, not to mention the stiff competition it is facing with GaN, which is much more mature in terms of devices. In this paper, recent progress in device applications of ZnO is discussed and a review of critical issues for realization of ZnO-based devices is given.

Light-emitting diodes (LEDs) have become quite a high-performance device of late and are revolutionizing the display and illumination sectors of our economy. Due to demands for better performance and reduced energy consumption there is a constant race towards converting every single electron hole pair in the device to photons and extracting them as well while using only the minimum required voltage. This raises the bar on GaN-based LEDs in terms of elimination of nonradiative recombination processes not just at low but just as importantly if not more at very high injection levels needed for high brightness sources, and design of heterostructures for efficient electron and hole recombination without carrier loss and voltage/photon energy conversion loss. The haunting efficiency droop observed in GaN-based LEDs at high injection levels has been attributed to nonradiative Auger recombination, but can be simply explained by electron spillover. Investigations of quantum well (QW) InGaN LED structures with different barrier heights, widths, and doping suggest that limited hole transport in the active region and the resulting electron spillover is responsible for efficiency droop at high injection levels. In this paper, highly critical, demanding, and challenging nature of high-efficiency high-brightness LEDs, in particular the basics surrounding the internal quantum efficiency of LED structures and the ongoing research/development, will be discussed.