Vulnerability-Fixing Commit Identification(VFCI) is a critical task in software security maintenance that aims to automatically identify code commits that patch security vulnerabilities. However, existing approaches face challenges in handling low-quality commit messages and entangled commits, which limit their identification performance. To address these issues, we propose VFCionX, a novel VFCI framework that integrates large and small language models in a collaborative architecture. VFCionX consists of three core modules: Message Classifier, Patch Classifier, and Ensemble Classifier. The Message Classifier employs a multi-source contextual augmentation strategy to enhance the quality of commit messages and fine-tunes the Qwen2.5-1.5B model, significantly improving classification performance in the textual modality. The Patch Classifier combines heuristic rules with a Qwen2.5-Coder-7B-driven file selector to filter noise from entangled commits, and incorporates a line-level feature extractor based on CodeBERT and CNN to capture local pattern differences between added and deleted code lines. The Ensemble Classifier integrates predictions from both channels using the AdaBoost algorithm, enhancing model robustness and generalization. Experimental results on five popular C/C++ repositories comprising 24,630 commits show that VFCionX achieves an F1-score of 81.47%, outperforming the best baseline by 9.42%. Ablation studies validate the effectiveness of each component, while sensitivity analysis reveals optimal parameter settings for balancing performance and noise resilience. This work provides a new and effective solution for robust vulnerability patch identification.