Integrating external tools with Large Language Models (LLMs) has emerged as a promising paradigm for accomplishing complex tasks.Since LLMs still struggle to effectively manage large tool collections, researchers have begun exploring retrieval-based methods to preselect the most relevant options, addressing input length and latency constraints.However, existing retrievers are often misaligned with toolcalling LLMs due to their separate training processes.This paper presents PORTS, a novel odds ratio preference optimization method for training retrievers aimed at tool selection.Using a perplexity-inspired preference signal from a frozen LLM, our approach fine-tunes a retriever to find helpful tools by optimizing the correlation between the selection probabilities and the downstream performances while jointly enforcing a contrastive semantic loss between documentation strings.The versatility of PORTS and its ability to significantly improve tool selection accuracy are demonstrated through extensive experiments on six datasets, two encoder models, and three LLMs with diverse prior knowledge.With low computational demands, our alignment process facilitates generalization to new queries and tools, proving valuable for practical applications with evolving toolsets.1